M A T E R I A L   S AF E T Y   D A T A S H E E T

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
   

   TRADE NAME .... : BLACK EXP 10459
   PRODUCT TYPE .. : InkJet ink; water based; nonflammable

   EMERGENCY PHONE (CHEMTREC 24 HOUR): 800-424-9300
   REASON FOR MSDS ISSUE: Formula modification
   MSDS VERSION: NA

2. COMPOSITION/INFORMATION ON INGREDIENTS

   CHEMICAL FAMILY: WATER/DYE MIXTURE

   HAZARDOUS COMPONENTS CAS # WEIGHT %
   PYRROLIDONE, 2- 616-45-5 1-10%
   No PEL established.
   UREA 57-13-6 < 2%
   No PEL established.

   The New Jersey Trade Secret Registration Number of proprietary ingredients is controlled by the KIMBERLY-CLARK PRINTING TECHNOLOGY product item number. Ingredients not precisely identified are proprietary or non-hazardous. Values are not product specifications.

3. HAZARDS IDENTIFICATION
   

   HMIS CODES: H F R P
   1 0 0 C

   INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
   None reported or known o exist for the product unless listed here:

   SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE:
   Eye/skin: May cause irritation.

   INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: May cause gastrointestinal irritation, vomiting, nausea, and diarrhea.

   ACUTE HEALTH HAZARDS: Moderate eye and skin irritation.

   MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known or determined for the product

   CHRONIC HEALTH HAZARDS: None known or determined for the product.

   CARCINOGENICITY: Product not tested. IARC, NTP, OSHA listed carcinogen components equal to or greater than 0.1% by weight will be listed in paragraph 2 and described as carcinogens, if any.

4. FIRST AID MEASURES
   

   EMERGENCY AND FIRST AID PROCEDURES:
   Swallowed: Do NOT induce vomiting. Call a doctor and contact local poison control center immediately.

   Eye contact: Flush eyes thoroughly with water. Seek medical attention if irritation persists.

   Skin contact: Wash contaminated areas with soap and water.

   Inhaled: Remove victim to fresh air.

5. FIRE FIGHTING MEASURES
   

   FLASH POINT: N/A (Non-flammable water based)

   METHOD USED: NA

   FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: NA UPPER: NA
   
   EXTINGUISHING MEDIA: NA
   
   SPECIAL FIREFIGHTING PROCEDURES: NA
   
   UNUSUAL FIRE AND EXPLOSION HAZARDS: NA
   
   6. ACCIDENTAL RELEASE MEASURES
   
   STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
   Soak up on paper or other absorbent and scoop into closed containers.
   Flush area with plenty of water.
   
   7. HANDLING AND STORAGE
   
   PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
   Storage temperature: Standard room temperature (68 degrees Fahrenheit).
   Special sensitivity: Heat, light, moisture.
   Precautions: Keep container closed. Store away from traffic.
   
   OTHER PRECAUTIONS
   None.
   
   8. EXPOSURE CONTROLS/PERSONAL PROTECTION
   
   RESPIRATORY PROTECTION: Not necessary.
   VENTILATION: Mechanical ventilation is acceptable.
   PROTECTIVE GLOVES: Rubber
   EYE PROTECTION: Goggles or safety glasses with side shields.
   OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Impervious clothing where skin
   contact is unavoidable; eyewash station.
   WORK/HYGIENIC PRACTICES: Avoid contamination of food, drink, etc. No
   smoking when handling.
   
   9. PHYSICAL AND CHEMICAL PROPERTIES
   
   BOILING POINT: > 200¯ F SPECIFIC GRAVITY (H2O=1): > 1
   VAPOR PRESSURE (mm of Hg): ND VAPOR DENSITY (AIR = 1): > 1
   EVAPORATION RATE (BUTYL ACETATE=1): > 1 MATERIAL VOC: Not measured
   PHYSICAL STATE: Liquid COLOR : BLACK
   ODOR: Mild SOLUBILITY IN WATER: Complete
   
   10. REACTIVITY
   
   STABILITY: Stable
   CONDITIONS TO AVOID: None known
   INCOMPATIBILITY (MATERIALS TO AVOID): Oxidizing materials and strong
   acids.
   HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Oxides of carbon and nitrogen.
   HAZARDOUS POLYMERIZATION: None
   
   11. TOXICOLOGICAL INFORMATION
   No information available.
   
   12. ECOLOGICAL INFORMATION
   No information available.
   ITEM NUMBER: F490500 DATE PRINTED: 08/26/1999 Page: 3
   
   13. DISPOSAL CONSIDERATIONS
   
   WASTE DISPOSAL METHOD
   Waste shall be disposed of in accordance with federal, state, and local
   environmental control regulations.
   
   14. TRANSPORTATION INFORMATION
   
   D.O.T. SHIPPING NAME: Not regulated.
   
   15. PRODUCT REGULATORY INFORMATION
   
   OSHA STATUS: Product not tested. It is not considered to be toxic per
   29CFR1910.1200 but is considered to be a skin/eye irritant.
   USA TSCA STATUS: This product meets the requirements of the Toxic
   Substances Control Act.
   INTERNATIONAL EXPORT/IMPORT STATUS: Not determined for every country.
   Contact KIMBERLY-CLARK PRINTING TECHNOLOGY for certification if
   required. Formulas are proprietary, so ingredient lists may only be
   released to Customs/Health offices designated to control trade secrets.
   SARA TITLE III SECTION 313 TOXIC CHEMICALS: Product not listed. SARA
   listed ingredients at or above De Minimis reporting levels are noted in
   paragraph 2, if any.
   RCRA HAZARDOUS WASTE NUMBER/STATUS: If discarded in its purchased form,
   this product would not be a federal hazardous waste either by listing or
   by characteristic. States, however, often have stricter criteria. Users
   should check with their state regulatory agencies for current hazardous
   waste criteria. Under RCRA it is the responsibility of the product user
   to determine at the time of disposal whether a material containing the
   product or derived from the product should be classified as a hazardous
   waste (40CFR261.20-24).
   OZONE-DEPLETING CHEMICALS: No regulated ingredients.
   
   NEW JERSEY
   REPORTABLE COMPONENTS CAS #
   WATER 7732-18-5
   DYE, NONHAZARDOUS SUPPLYPROP54
   PYRROLIDONE, 2- 616-45-5
   UREA 57-13-6
   BIOCIDE FL PROP 176
   
   The New Jersey Trade Secret Registration Number of proprietary
   ingredients is controlled by the KIMBERLY-CLARK PRINTING TECHNOLOGY
   product item number.
   
   CALIFORNIA PROPOSITION 65 (CARCINOGENS):
   REPORTABLE COMPONENTS CAS # WEIGHT %
   . NONE UNLESS LISTED, AS FOLLOWS:
   
   CALIFORNIA PROPOSITION 65 (REPRODUCTIVE TOXINS):
   REPORTABLE COMPONENTS CAS # WEIGHT %
   . NONE UNLESS LISTED, AS FOLLOWS:
   
   

6. OTHER INFORMATION

   All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. This information is believed to be correct, but does not purport to be all inclusive and shall be used only as a guide. KIMBERLY-CLARK PRINTING TECHNOLOGY, INC. makes no warranty, express or implied, as to the accuracy or completeness of this information. It is the user's responsibility to determine the suitability of this information for the adoption of necessary safety precautions and/or compliance with federal, state, and local laws and regulations.